Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1607597 | Journal of Alloys and Compounds | 2015 | 8 Pages |
Abstract
Using graphene oxide and hydrous ruthenium chloride as starting materials, RuO2/graphene composites were prepared via a hydrothermal reaction under different precipitation conditions by using ammonium carbonate, urea, and sodium hydrate as precipitants. The morphology and structure of the RuO2/graphene composites were characterized by SEM, TEM, XRD. Cyclic voltammetry, galvanostatic charge-discharge, and impedance measurements were carried out to test the electrochemical performance. The results revealed that the veil-like RuO2/graphene composite prepared by sodium hydrate precipitation showed better capacitance performance than a particle-like composite prepared by ammonium carbonate and urea precipitation. A disproportionation reaction from Ru3+ to Ru and RuO2 took place in the RuO2/graphene composite when using CO(NH2)2 as the precipitant. The RuO2/graphene composite using sodium hydrate as the precipitant exhibited the optimum electrochemical performance with superior specific capacitance of 528.5 F gâ1 at 0.1 A gâ1, minimum resistance (0.4 Ω), and excellent rate performance and cycling stability, suggesting the synergetic effects of the Ru(OH)δCl3âδ precursors and graphene oxide during the hydrothermal process.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Xian Leng, Jianpeng Zou, Xiang Xiong, Hanwei He,