| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1609179 | Journal of Alloys and Compounds | 2015 | 7 Pages |
•The new single crystals ZnCr2Se4 doped by tin were successfully synthesized.•ZFC and FC splitting for all investigated crystals was observed.•Spin-glass-like behaviour for a large Sn content was discovered.
The single crystals of ZnCr2Se4 doped with tin ions having contents of 0.92, 1.01 and 1.26 located in the octahedral sites of the spinel structure were successfully synthesized. The ac and dc magnetic measurements, and as well as the specific heat studies showed the spin-glass-like behaviour for all compositions below the freezing temperatures Tf = 13–15 K. Both high positive values of the paramagnetic Curie–Weiss temperature, decreasing from 112 K to 58 K as the Sn-content increases, and the lack of a metamagnetic transition (characteristic for the ZnCr2Se4 matrix) suggest a strong ferromagnetic exchange in the (0 0 1) planes which is randomly frozen below Tf between the spins in adjacent (0 0 1) planes. These effects are interpreted in terms of the exchange integral of the spin-glass system including non-stoichiometry, spin and structural defects.
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