Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1610625 | Journal of Alloys and Compounds | 2014 | 4 Pages |
Abstract
A gallium selenide (GaSe) compound with a layered crystal structure was synthesized via chemical reduction with hydrazine solution, and its electrochemical characteristics, including reaction mechanisms for lithium ion battery (LIB) anodes, are presented in this work. The cyclic voltammetry and ex-situ X-ray diffraction results indicated that some of lithium ions were intercalated/deintercalated into GaSe lattices such as graphite, and others reacted with the decomposed gallium to form LixGa, followed by an alloying/dealloying process. The GaSe anode showed a discharge capacity as high as 760 mA h gâ1 at the 50th cycle, with excellent cyclic stability due to the highly reversible reactions enabled by its layered structure.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Jae-Hun Jeong, Dong-Won Jung, Eun-Suok Oh,