Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1611116 | Journal of Alloys and Compounds | 2014 | 6 Pages |
Abstract
Ga-doped 3D urchin-like ZnO structures with different morphologies have been synthesized by thermal evaporation with different molar ratio gallium oxide as the dopant source. The morphology, microstructure and chemical state were determined by field emission scanning electron microscopy, X-ray diffraction, high-resolution transmission electron microscopy, and X-ray photoelectron spectroscopy (XPS). The investigation confirmed that the morphologies of the 3D urchin-like ZnO structure had a significant transform with the increase of the dopant. The XPS result indicates that Ga is incorporated into the ZnO lattice. photoluminescence emission peak has been found to be quenched remarkably caused by 5Â mol% Ga2O3 dopant. The reason of the emission quench is discussed by means of density functional theory calculations. It is found that O-2p states slightly hybridize with Zn-3d and Ga-4s, Ga-4p states giving rise to the conduction band downward and introduction of the correlative impurity levels, which will result in the increase of non-radiative transition.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Yu Lingmin, Fan Xinhui, Lei Man, Wei Jiansong, Jin Yao hua, Yan Wen,