Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1613361 | Journal of Alloys and Compounds | 2013 | 4 Pages |
Abstract
⺠Reorientations of BH4â anions were probed via neutron fixed-window scans (FWSs). ⺠Both bulk and destabilized alkali-metal borohydride MBH4 compounds were measured. ⺠The T profile of the FWS was a good indicator of BH4â reorientational mobilities. ⺠BH4â mobility in MBH4 increased considerably with cation size from Li+ to Cs+. ⺠Nanoconfined and LiI-alloyed LiBH4 showed enhanced BH4â mobilities versus bulk LiBH4.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Terrence J. Udovic, Nina Verdal, John J. Rush, Daniel J. De Vries, Michael R. Hartman, John J. Vajo, Adam F. Gross, Alexander V. Skripov,