| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1614113 | Journal of Alloys and Compounds | 2013 | 8 Pages |
Abstract
Ba4Na2Zn4(B3O6)2(B12O24) contains complicated porous anionic layers composed of ZnO4 tetrahedra, [B3O6]3â rings with notation of 3[3Î], and [B12O24]12â groups built up from four BO4 tetrahedra and eight BO3 triangles with notation of 2Â ÃÂ {2Â ÃÂ (3[2ÎÂ +Â 1T])}. The anionic layers stack along c-axis, with the intralayer open channels and interlayer void spaces occupied by Na+ or Ba2+ cations to balance charge.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
![Synthesis, crystal structure, spectrum properties, and electronic structure of a new three-borate Ba4Na2Zn4(B3O6)2(B12O24) with two isolated types of blocks: 3[3Î] and 3[2ÎÂ +Â 1T]](/preview/png/1614113.png "First Page Preview: Synthesis, crystal structure, spectrum properties, and electronic structure of a new three-borate Ba4Na2Zn4(B3O6)2(B12O24) with two isolated types of blocks: 3[3Î] and 3[2ÎÂ +Â 1T]")
Authors
Xuean Chen, Yanjun Chen, Chong Sun, Xinan Chang, Weiqiang Xiao,