Article ID Journal Published Year Pages File Type
1615136 Journal of Alloys and Compounds 2013 4 Pages PDF
Abstract

The effect of poly (3,4-ethylene dioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) interlayer on the Schottky barrier parameters of Pt/n-type Ge Schottky contacts was investigated. The PEDOT:PSS interlayer in between Pt and n-type Ge influences the space charge region of the Pt/n-type Ge Schottky junction, leading to increase in the barrier height. Due to interface dipoles and lateral barrier inhomogeneities caused by the presence of PEDOT:PSS interlayer, Pt/PEDOT:PSS/n-type Ge Schottky contact showed a deviation from the ideal thermionic emission model of the carrier transport at the metal/semiconductor junction. From the reverse current–voltage (I–V) characteristics, the Poole–Frenkel emission and Schottky emission were found to be the dominating carrier conduction mechanisms of Pt/PEDOT:PSS/n-type Ge Schottky contact at lower and higher reverse biases, respectively.

► PEDOT:PSS interlayer led to increase in Schottky barrier height of Pt/n-Ge Schottky diodes. ► Inhomogeneity of Schottky barrier heights across the contact caused by PEDOT:PSS interlayer. ► Transition of carrier conduction mechanism from Poole–Frenkel emission to Schottky emission at a higher bias range.

Related Topics
Physical Sciences and Engineering Materials Science Metals and Alloys
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