Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1615257 | Journal of Alloys and Compounds | 2013 | 8 Pages |
The Ca(ZrxTi1−x)O3 ceramic was prepared by solid state reaction method. Structural characterizations were performed by means of XRD, FT-Raman and FTIR. The formation of monophasic compounds obtained in the composition x = 0.0–0.2 and 0.9–1.0 were confirmed from XRD, FT-Rama and FTIR spectroscopy. However the compositions between x = 0.3 and 0.8 showed presence of mixed phase or secondary phase. The microwave dielectric constant, Q × f and τf changed from 158 to 141, 4321 to 5945 and from 843.9 to 732.33 ppm/°C respectively in the composition between x = 0.0 and 0.2. The anomalous results of dielectric constant, Q × f and τf values in the composition between x = 0.3 and 0.8 were observed. The microwave dielectric constant and τf were found to be decreased from 42 to 27 and 81.75 to −19.98 ppm/°C in the composition between x = 0.9 and 1.0 respectively. The Q × f values increased from 10728 to 16543 with the increase of x value from 0.9 to 1.0. The dielectric resonator antenna (DRA) was investigated experimentally and numerically using a monopole antenna through an infinite ground plane and Ansoft’s high frequency structure simulator software, respectively. The required resonance frequency and bandwidth of DRA were investigated in the composition between 0 ≤ x ≤ 1.0.
► XRD and Raman spectroscopy are used to study the solubility limit of Ca(ZrxTi1−x)O3 ceramic. ► TE01δ cavity method is used for study of microwave properties of Ca(ZrxTi1−x)O3 ceramic. ► Microwave dielectric constant, Q × f and τf changed from 158 to 141, 4321 to 5945 and from 843.9 to 732.33 ppm/°C, respectively in the composition between x = 0.0 and 0.2. ► The microwave dielectric constant and τf were found to be decreased from 42 to 27 and 81.75 to −19.98 ppm/°C in the composition between x = 0.9 and 1.0 respectively.