Article ID Journal Published Year Pages File Type
1615855 Journal of Alloys and Compounds 2012 9 Pages PDF
Abstract
► The unit cell of Sr2Fe2−xMoxO6 increased when x changed from 0.50 to 0.65. ► The increase in unit cell results from a cubic to tetragonal transformation. ► Fe K- and Mo K-edge XANES show reduction of Fe3+ to Fe2+/3+ and Mo+6 to Mo5+/6+. ► Reduction of Fe3+ drives the cubic to tetragonal unit cell transformation.
Related Topics
Physical Sciences and Engineering Materials Science Metals and Alloys
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