Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1616019 | Journal of Alloys and Compounds | 2012 | 7 Pages |
Abstract
⸠The metathesis reaction between NaBH4 and TM-chlorides does not proceed under all experimental conditions. ⸠Clâ to BH4â ion substitution is systematically induced by ball milling in NaBH4 samples when using a variety of transition metal (TM) chlorides. ⸠This leads to Na(BH4)1âxClx borohydrides, with x ranging from x = 0.69 to 0.92 depending on the TM. ⸠Our experimental work evidences the difficulties encountered for the successful synthesis of mixed metal borohydrides by mechano-chemical methods, which remain a challenge.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Isabel Llamas-Jansa, Nadir Aliouane, Stefano Deledda, Jon Erling Fonneløp, Christoph Frommen, Terry Humphries, Klaus Lieutenant, Sabrina Sartori, Magnus H. Sørby, Bjørn C. Hauback,