Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1617143 | Journal of Alloys and Compounds | 2011 | 4 Pages |
Martensitic transformation in a highly ordered Fe3Pt has been investigated by magnetization and X-ray diffraction measurements. We confirmed that a new type of face-centered tetragonal (FCT) martensite phase appears below 60 K in Fe3Pt with a degree of order S = 0.88. The tetragonality c/a gradually increases with decreasing temperature, and is approximately 1.005 at 10 K. This is in contrast to the tetragonality c/a < 1 generally observed in the FCT martensite with a degree of order less than 0.8. The spontaneous magnetization increases in association with the transformation.
• TEM observations at room temperature reveal that the specimen is a single phase of L12-type structure. • The spontaneous magnetization and magnetic susceptibility curves of Fe3Pt with S = 0.88 have bend points at 60 K. • XRD measurements reveal that this alloy exhibits a martensitic transformation to FCT and the transformation temperature is 60 K. • The tetragonality c/a is larger than unity in the FCT martensite. • This tetragonality is in contrast to the tetragonality c/a < 1generally observed in the FCT martensite with S < 0.8.