| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1617808 | Journal of Alloys and Compounds | 2011 | 6 Pages |
Abstract
⺠FT-FIR spectra and diffraction patterns vs. temperature showed that phase transition is probably associated with a change of the crystal structure. ⺠Fast stochastic molecular reorientational motions of NH3 ligands do not change their character in the wide temperature range. ⺠High temperature phase is dynamically orientationally disordered phase. ⺠Low value of the activation energy for NH3 ligands reorientation suggests that this motion proceeds through the translation-rotation coupling.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
2 studied by neutron scattering methods and far infrared spectroscopy](/preview/png/1617808.png "First Page Preview: Phase transition in [Ca(NH3)6](ClO4)2 studied by neutron scattering methods and far infrared spectroscopy")
Authors
Joanna HetmaÅczyk, Åukasz HetmaÅczyk, Anna MigdaÅ-Mikuli, Edward Mikuli, Ireneusz Natkaniec,