Article ID Journal Published Year Pages File Type
1618013 Journal of Alloys and Compounds 2010 6 Pages PDF
Abstract

The diffusion and site occupation of hydrogen in the monohydride phase of V1−xMox–H (0 ≤ x ≤ 0.1) were studied by means of 1H nuclear magnetic resonance (NMR). Hydrogen atoms in VH0.68 occupied the octahedral (O) sites in a body centered tetragonal (BCT) structure. The addition of Mo to V reduced the activation energy for hydrogen diffusion, EH, for the O sites. In V0.9Mo0.1H0.68 hydrogen atoms occupied both the O and tetrahedral (T) sites, which was demonstrated by two components observed in the temperature dependence of the 1H spin-lattice relaxation time. The value of EH for the T sites was lower than that for the O sites. Hydrogen atoms in V0.9Mo0.1H0.68 diffused faster than those in VH0.68.

Research highlights▶ Site occupation of hydrogen in the monohydride phase of V1−xMoxH0.68 (0 ≤ x ≤ 0.1). ▶ Temperature dependence of the 1H spin-lattice relaxation time in V1−xMoxH0.68 (0 ≤ x ≤ 0.1). ▶ Activation energy for hydrogen diffusion for the octahedral and tetrahedral sites.

Related Topics
Physical Sciences and Engineering Materials Science Metals and Alloys
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