Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1618413 | Journal of Alloys and Compounds | 2011 | 5 Pages |
LiFePO4/C active material was synthesized using an ultrasonic-assisted rheological phase method. In addition, polyvinyl butyral (PVB) was added in various concentrations to provide carbon coating on the surface of the LiFePO4 particles for enhanced electrical conductivity. The crystal structure, morphology, and carbon coating layer of the synthesized LiFePO4/C was analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), respectively. The electrochemical performance of LiFePO4/C, such as initial capacity, rate capability, cycling performance and EIS, were also evaluated. The synthesized particle had a size range of 100–150 nm and a carbon layer of about 8 nm. The LiFePO4/C (5 wt% PVB) delivered an initial discharge capacity of 167.5 mAh/g at a 0.1 C rate. It also showed an excellent capacity retention ratio of 100% after the 50th charging/discharging. EIS results demonstrate that the charge transfer resistance of the sample decreases greatly by coating with 5 wt% PVB.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► LiFePO4/C active material was synthesized using an ultrasonic-assisted rheological phase method. ► In addition, polyvinyl butyral (PVB) was added in various concentrations to provide carbon coating on the surface of the LiFePO4 particles for enhanced electrical conductivity. ► The synthesized particle had a size range of 100 ∼ 150 nm and a carbon layer of about 8 nm. ► The LiFePO4/C (5 wt% PVB) delivered an initial discharge capacity of 167.5 mAh/g at a 0.1 C rate.