Article ID Journal Published Year Pages File Type
1618416 Journal of Alloys and Compounds 2011 6 Pages PDF
Abstract

Visible light photoactive AgCl/polypyrrole (PPy) composites were prepared via the reaction between excessive Ag+ and Cl− ions in the presence of PPy. The AgCl/PPy composites were systematically characterized using Fourier transform infrared (FTIR) spectroscopy, Raman spectra, X-ray diffraction (XRD), Scanning electron microscope (SEM), Transmission electron microscope (TEM) and Thermal gravity analysis (TGA). It was found that face-centered cubic AgCl nanocrystallite and 0.2 wt% PPy component existed in the composite and spherical AgCl/PPy nanoparticles were in the range of 200–600 nm. The AgCl/PPy composites showed higher visible light-driven photocatalytic activity and stability than that of AgCl. A photoreduction mechanism was postulated for AgCl/PPy photocatalyst on dye methyl orange (MO). The used AgCl/PPy photocatalyst was facilely regenerated by an oxidation process in aqueous FeCl3 solution.

Graphical abstractAgCl/PPy composite exhibits improved photocatalytic performance and high stability under visible light.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► AgCl/(PPy) nanocomposites as visible light driven photocatalyst. ► Composites exhibited high visible light-driven photocatalytic activity and stability. ► Photocatalytic process on MO followed photoreduction mechanisms. ► Used photocatalyst can be regenerated in aqueous FeCl3 solution.

Related Topics
Physical Sciences and Engineering Materials Science Metals and Alloys
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