Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1618416 | Journal of Alloys and Compounds | 2011 | 6 Pages |
Visible light photoactive AgCl/polypyrrole (PPy) composites were prepared via the reaction between excessive Ag+ and Cl− ions in the presence of PPy. The AgCl/PPy composites were systematically characterized using Fourier transform infrared (FTIR) spectroscopy, Raman spectra, X-ray diffraction (XRD), Scanning electron microscope (SEM), Transmission electron microscope (TEM) and Thermal gravity analysis (TGA). It was found that face-centered cubic AgCl nanocrystallite and 0.2 wt% PPy component existed in the composite and spherical AgCl/PPy nanoparticles were in the range of 200–600 nm. The AgCl/PPy composites showed higher visible light-driven photocatalytic activity and stability than that of AgCl. A photoreduction mechanism was postulated for AgCl/PPy photocatalyst on dye methyl orange (MO). The used AgCl/PPy photocatalyst was facilely regenerated by an oxidation process in aqueous FeCl3 solution.
Graphical abstractAgCl/PPy composite exhibits improved photocatalytic performance and high stability under visible light.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► AgCl/(PPy) nanocomposites as visible light driven photocatalyst. ► Composites exhibited high visible light-driven photocatalytic activity and stability. ► Photocatalytic process on MO followed photoreduction mechanisms. ► Used photocatalyst can be regenerated in aqueous FeCl3 solution.