Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1620462 | Journal of Alloys and Compounds | 2010 | 6 Pages |
Abstract
Site occupancies of Co, Y (Y = Ti, V, Cr, Mn and Fe) and Ga atoms for the L21 phase in Co2YGa alloys annealed at 773 K were precisely investigated by powder neutron diffraction measurement. While Co atoms in all the five alloys almost perfectly occupy the x (2a) site, the occupancy of the z (4b) site by Ga atoms depends on the kind of Y atom, and it decreases with increasing number of valence electrons except for Co2CrGa alloy. Degrees of long-range order on the z site occupancy of Ga atoms experimentally determined for all the alloys are in good agreement with those thermodynamically estimated from their order-disorder transition temperatures using the Bragg-Williams-Gorsky approximation.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
R.Y. Umetsu, K. Kobayashi, R. Kainuma, Y. Yamaguchi, K. Ohoyama, A. Sakuma, K. Ishida,