Article ID Journal Published Year Pages File Type
1620866 Journal of Alloys and Compounds 2010 7 Pages PDF
Abstract

By DTA, X-ray diffraction, EMF methods and microhardness measurements, the phase equilibria on the concentration sections Tl5Te3-Tl4PbTe3-Tl9BiTe6 (I), Tl2Te-Tl4PbTe3-Tl9BiTe6 (II), Tl5Te3-Tl9NdTe6-Tl9BiTe6 (III) and Tl2Te-Tl9NdTe6-Tl9BiTe6 (IV) of the multinary systems Tl-Pb(Nd)-Bi-Te were investigated. A number of isopleth sections, projections of liquidus and solidus surfaces of the systems (I)–(IV) were constructed. The concentration dependences of crystal lattice parameters, microhardness and of partial thermodynamic functions of thallium (ΔG¯,ΔH¯,ΔS¯) in alloys were determined. The investigated systems are characterized by formation of continuous (I, III) or wide (II, IV) areas of solid solutions based on Tl5Te3 compound.

Related Topics
Physical Sciences and Engineering Materials Science Metals and Alloys
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