Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1621158 | Journal of Alloys and Compounds | 2009 | 4 Pages |
Abstract
Colloidally stable sub-3 nm Eu2O3 and Gd2O3:Eu3+ nanocrystals have been synthesized via a hot solution phase technique. Optical properties of the nanocrystals are studied as a function of size. Both nanocrystal compositions exhibit a new optical signature, an emission peak at 620 nm. Intensity modulation of this peak has been observed for all nanocrystal sizes, suggesting surface-dependent or crystal-field dependent effect. Photoluminescence intensity of smaller Eu2O3 nanocrystals was comparable to that of the Gd2O3:Eu3+ nanocrystals.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Sameer V. Mahajan, James H. Dickerson,