Article ID Journal Published Year Pages File Type
1622399 Journal of Alloys and Compounds 2009 4 Pages PDF
Abstract
The five-stage devitrification of rapidly quenched Al89Ni6Sm5 and Al86Ni6Sm5Pd3 ribbons has been studied by differential scanning calorimetry and electrical resistivity measurements. The formed phases have been identified by X-ray diffraction, transition electron microscopy and high-temperature differential thermal analysis. In the first stage spherical fcc-Al nano-particles develop with a very high density. After the sequential formation and modification of the grown phases the equilibrium fcc-Al, Al3Ni, Al3Sm, Al4Sm and Al11Sm3, eventually, equivalent with the equilibrium phases in related master-alloys have been developed. The stabilizing effect of Pd on both thermodynamics and kinetics of individual transformations has been analyzed.
Related Topics
Physical Sciences and Engineering Materials Science Metals and Alloys
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