| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1625873 | Journal of Alloys and Compounds | 2007 | 4 Pages |
Abstract
The air stable uranyl and neptunyl phosphine oxide complexes act as good starting material to prepare the air and moisture sensitive phosphinimines species and show a preference for N-donor ligands. Calculations confirmed those observations and proved the UN bond to be stronger than the UO bond. To continue our investigations on transuranyl chemistry, the complexes PuO2Cl2(R3PO)2 have been synthesised as well as new amides species of NpO22+ and PuO22+ characterised by NMR spectroscopy.
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Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Stéphanie M. Cornet, Iain May, Mark J. Sarsfield, Nikolas Kaltsoyannis, Jonas Haller, Christophe Den Auwer, Daniel Meyer,