Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1626015 | Journal of Alloys and Compounds | 2007 | 4 Pages |
A portion of the isothermal section (1173 K) of the phase diagram of the Gd–Co–Al ternary system (up to 33.3 at.% Gd) were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersion spectroscopy (EDS) techniques. Fourteen single-phase regions (including solid solution regions of the binary compounds), twenty-five two-phase regions and twelve three-phase regions were found to exist at this isothermal section. In the GdCo2–GdAl2 system, the existence of the GdCo0.74Al1.26 phase is identified and it has a composition range of 30–45 at.% Al, the maximum solid solubility of Al in GdCo2 is about 15 at.%, and Co in GdAl2 is about 16 at.%. Besides, the maximum solid solubility of Al in Co, Gd2Co17 and GdCo5 is about 6, 17 and 25 at.%, respectively, the maximum solid solubility of Gd in Co, CoAl is below 2 at.% and the solid solubility range is from 47 to 61 at.% Al in CoAl phase. In this work, no new ternary compounds were observed.