Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1626200 | Journal of Alloys and Compounds | 2007 | 4 Pages |
Abstract
It has been shown previously that, by using many-body perturbation theory, the electric dipole moment for transitions between exact energy eigenstates dominated by 4fN and 4fNâ15d configurations can be calculated with an effective electric dipole operator composed of one- and two-body interactions. Especially, the one-body part of this effective operator is proportional to the original electric dipole moment, but with a reduced radial integral ã5d|r|4fãeff = (1 â δ)ã5d|r|4fã. We obtain the values of parameters charactering the effective operator for all the lanthanide trivalent and divalent ions via a pseudorelativistic Hartree-Fock calculation. The trend of these parameters is analyzed. The impact of the values obtained on the reinterpretation of literature emission lifetimes is given.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Tao Chen, Chang-Kui Duan, Shangda Xia,