| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1627513 | Journal of Alloys and Compounds | 2006 | 5 Pages |
Abstract
The quaternary nitride LiCaGaN2 was synthesized from the elements and an excess of sodium and gallium at 900° C in a sealed niobium tube. LiCaGaN2 is colorless and crystallizes in the monoclinic space group P21/c(Z=4) with a=5.790(1),b=6.969(1),c=5.895(1)a=5.790(1),b=6.969(1),c=5.895(1) Å; β=90.037(5)°β=90.037(5)°. The structure contains the nitridogallate species |∞2 Ga2N2N4/2, which is formed by condensing edge-sharing GaN4 tetrahedral pairs.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Mark S. Bailey, Francis J. DiSalvo,