Article ID Journal Published Year Pages File Type
1627600 Journal of Alloys and Compounds 2006 5 Pages PDF
Abstract

Purposely designed ionic liquids can be excellent solvents for spectroscopic studies of rare earth compounds. Absorption, excitation and emission spectra of LnI3 (Ln = Nd, Dy and Tb) in the ionic liquid 1-dodecyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide are presented. Electronic transitions were assigned from the energy level diagrams for Ln(III). Emission lifetimes for DyI3 in [C12mim][Tf2N] are discussed. Traces of water dramatically reduce the otherwise long lifetimes and comparatively high quantum yields.

Related Topics
Physical Sciences and Engineering Materials Science Metals and Alloys
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