Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1627600 | Journal of Alloys and Compounds | 2006 | 5 Pages |
Abstract
Purposely designed ionic liquids can be excellent solvents for spectroscopic studies of rare earth compounds. Absorption, excitation and emission spectra of LnI3 (Ln = Nd, Dy and Tb) in the ionic liquid 1-dodecyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide are presented. Electronic transitions were assigned from the energy level diagrams for Ln(III). Emission lifetimes for DyI3 in [C12mim][Tf2N] are discussed. Traces of water dramatically reduce the otherwise long lifetimes and comparatively high quantum yields.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Anja-Verena Mudring, Arash Babai, Sven Arenz, Ralf Giernoth, K. Binnemans, Kris Driesen, Peter Nockemann,