| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1627964 | Journal of Alloys and Compounds | 2006 | 9 Pages |
Abstract
A series of nine bulk crystals of the Zn4 − xCdxSb3 compounds (x = 0–2.00 with 0.25 step) has been successfully synthesized and the detailed crystal structure has been refined by powder XRD study using the Rietveld method including the quantitative analysis. The substitution limit of the Cd atoms for the Zn4 − xCdxSb3 system has been extended to x = 2.00 by employing the vacuum casting method without annealing. The purities and densities of the bulk crystals exceeded approximately 96 mass% and 95% of XRD density, respectively. The lattice parameters of the a and c-axes in the system increase linearly with increasing Cd content x with obeying the Vegard law.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Takeshi Souma, Michitaka Ohtaki,