Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1630421 | Journal of University of Science and Technology Beijing, Mineral, Metallurgy, Material | 2008 | 6 Pages |
Abstract
Submicron copper microcrystal was synthesized by reducing Cu2O with hydrazine hydrate as reducer in aqueous solution, and was characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The shapes of copper microcrystal depend on additives. Cubic copper particles were observed when the inorganic salt containing Clâ, such as NH4Cl, NaCl, or KCl, was added into the reaction system. By combined use of NH4Cl and polyvinylpyrrolidone (PVP), the proportion of cubic copper particle number exceeded 90%, and the particle size is 0.1â¼0.5 μm. While other inorganic salt without Clâ, such as Na2SO4 or (NH4)2SO4, had little effect on the shapes of the copper particles. The growth mechanism of metallic copper crystal in aqueous solution was analyzed. It is suggested that the formation of cubic copper crystals is ascribed to the selective adsorption of Clâ on copper crystal (100) faces.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Minyi Hu, Kanggen Zhou, Chongguo Wang, Rui Xu,