Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1635108 | Rare Metals | 2007 | 7 Pages |
Abstract
The complex of Eu(III) with 1-(6-hydroxy-1-naphthyl)-1,3-butanedione (HNBD) was prepared for the first time and characterized by elemental analysis, IR, UV, fluorescence spectrum, and DTA-TG-DTG techniques. The IR and UV-visible spectra showed that Eu(III) ion was coordinated to the HNBD ligand. The fluorescence spectrum showed the presence of Eu3+ characteristic emission. The TG-DTA-DTG curves showed that the thermal decomposition of the anhydrous complex was a two-stage process and the final residue was Eu2O3. The thermal decomposition kinetic parameters of the complex were evaluated from TG-DTG data by using three kinds of integral methods (Coat-Redfern equation, Horowitz and Metzger equation, Madhusudanan-Krishnan-Ninan equation). The kinetic parameters of the first stage are E* = 164.02 kJ·molâ1, A = 1.31 à 1015 sâ1, ÎS* = 42.27 J·Kâ1·molâ1, ÎH* = 159.51 kJ·molâ1, ÎG* = 136.54 kJ·molâ1, and n = 3.1, those of the second stage are E* = 128.52 kJ·molâ1, A = 1.44 à 106 sâ1, ÎS* = - 136.89 J·Kâ1·molâ1, ÎH* = 120.41 kJ·molâ1, ÎG* = 283.85 kJ·molâ1, and n = 1.1.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Dunjia WANG, Chunyang ZHENG, Tingquan SUN,