Article ID Journal Published Year Pages File Type
1635397 Rare Metals 2006 5 Pages PDF
Abstract
Quantum chemical calculation was carried out to choose a promoter which can reduce the poisoning of V2O5/TiO2 catalysts by SO2. Several atoms were chosen as candidates and new catalysts were synthesized by impregnation method. The NOx conversion rate was measured at temperatures between 100 and 400 °C and poisoning effect was investigated. The most promising candidate promoter, Se, was excluded because of its high vapor pressure. On the other hand, Sb shows best promoting properties. Sb promoted catalyst reaches the maximum NOx conversion rate at 250 °C. It also shows considerably enhanced resistance to poisoning of V2O5/TiO2 catalysts by SO2.
Related Topics
Physical Sciences and Engineering Materials Science Metals and Alloys
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