Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1635397 | Rare Metals | 2006 | 5 Pages |
Abstract
Quantum chemical calculation was carried out to choose a promoter which can reduce the poisoning of V2O5/TiO2 catalysts by SO2. Several atoms were chosen as candidates and new catalysts were synthesized by impregnation method. The NOx conversion rate was measured at temperatures between 100 and 400 °C and poisoning effect was investigated. The most promising candidate promoter, Se, was excluded because of its high vapor pressure. On the other hand, Sb shows best promoting properties. Sb promoted catalyst reaches the maximum NOx conversion rate at 250 °C. It also shows considerably enhanced resistance to poisoning of V2O5/TiO2 catalysts by SO2.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Phil HA Heon, Hyo CHUNG Soon, Joo OH Young,