Article ID Journal Published Year Pages File Type
1635633 Transactions of Nonferrous Metals Society of China 2016 6 Pages PDF
Abstract
Bi26Mo10O69 nanopowder was prepared by hydrothermal method and used as a surface modification material for oxygen separation membrane to enhance oxygen permeability. Thermal decomposition behavior and phase variation of the precursor were investigated by thermal analyzer (TG-DSC) and high-temperature X-ray diffraction (HT-XRD). Bi26Mo10O69 porous layer was coated on the air side of BaCo0.7Fe0.2Nb0.1O3-δ (BCFN) oxygen permeable membrane by dipping method. In the partial oxidation experiment of coke oven gas (COG), the Bi26Mo10O69-coated BCFN membrane exhibits higher oxygen permeability and CH4 conversion than the uncoated BCFN membrane. When the thickness of BCFN membrane was 1 mm and the COG and air fluxes were 120 and 100 mL/min, the oxygen permeation flux reached 16.48 mL/(min·cm2) at 875 °C, which was 16.96% higher than the uncoated BCFN membrane. Therefore, Bi26Mo10O69 porous layer on the air side will be promising modification coating on the oxygen permeability of BCFN membrane.
Related Topics
Physical Sciences and Engineering Materials Science Metals and Alloys
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