Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1638100 | Transactions of Nonferrous Metals Society of China | 2011 | 10 Pages |
The hot corrosion behaviors of as-cast and preoxidized Ni-xCr-6.8Al based alloys in the mixture of Na2SO4+25%NaCl at 873 K were studied. The results show that the mass loss of Ni-xCr-6.8Al based alloys decreases with the increase of Cr content. Preoxidation improves the resistance to corrosion regardless of the concentration of Cr. The kinetics of as-cast Ni-12Cr-6.8Al and Ni-16Cr-6.8Al based alloys fits the parabolic law well, while that of the as-cast Ni-20Cr-6.8Al based alloy fits the power law. The kinetics of all the preoxidized samples obey the logarithmic law. The mechanism of the as-cast alloys can be well explained by the acid-base melting model. The behavior of the preoxidized alloys is found to be mainly determined by the properties of the oxide layer formed during the preoxidation to a large extend.