| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1640096 | Transactions of Nonferrous Metals Society of China | 2007 | 5 Pages |
To improve the performance of LiFePO4, single phase Li1-4xTixFePO4/C (x=0, 0.005, 0.010, 0.015) cathodes were synthesized by solid-state method. A certain content of glucose was used as carbon precursor and content of carbon in every final product was about 3.5%. The samples were characterized by X-ray diffraction(XRD), scanning electron microscopy observations(SEM), charge/discharge test, carbon analysis and electrochemical impedance spectroscopy(EIS). The results indicate that the prepared samples have ordered olivine structure and doping of the low concentration Ti4+ does not affect the structure of the samples. The electrochemical capabilities evaluated by charge-discharge test show that the sample with 1% Ti4+ (molar fraction) has good electrochemical performance delivering about an initial specific capacity of 146.7 mAΔh/g at 0.3C rate. Electrochemical impedance spectroscopy measurement results show that the charge transfer resistance of the sample could be decreased greatly by doping an appropriate amount Ti4+.
