Article ID Journal Published Year Pages File Type
1649843 Materials Letters 2009 4 Pages PDF
Abstract

Ceramics in a PZT–PCN system with the formula (1 − x)Pb(Zr1/2Ti1/2)O3–(x)Pb(Co1/3Nb2/3)O3, where x = 0.0, 0.1, 0.2, 0.3, 0.4, 0.5, and 1.0, were prepared using a solid-state mixed-oxide technique with columbite−CoNb2O6 and wolframite−ZrTiO4 precursors. The crystal structure of the specimens studied with X-ray diffraction (XRD) analysis showed a coexistence between tetragonal and pseudo cubic phases at composition x = 0.2. The SEM micrograph showed that the average grain size significantly decreased with increasing PCN content. A maximum dielectric constant was observed at composition x = 0.2, while the transition temperature strongly decreased with increasing PCN content. All ceramics also showed diffused phase transition behaviors with a minimum diffusivity at x = 0.2. The morphotropic phase boundary (MPB) lay at the 0.8PZT–0.2PCN composition.

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Physical Sciences and Engineering Materials Science Nanotechnology
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