Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1651182 | Materials Letters | 2008 | 4 Pages |
In(OH)3 and InOOH crystals were synthesized at different temperatures by diglycol-mediated solvothermal processes. Their phase structures, morphologies and growth mechanisms were investigated by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and chemical analysis. A small quantity of ((H2O)3In)Cl3 was observed in In(OH)3 crystals, which resulted in formation of In(OH)3 crystals with complicated shapes and morphologies. In(OH)3 grew along [1 0 0] direction, while ((H2O)3In)Cl3 grew preferentially along several crystal directions. In-situ transformation from both In(OH)3 and ((H2O)3In)Cl3 to InOOH developed at temperature higher than 140 °C, consequently InOOH nanoparticles partly inherited the morphologies of In(OH)3 nanorods.