Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1651983 | Materials Letters | 2008 | 4 Pages |
Abstract
A silicalite/mordenite bilayered self-supporting membrane with disc-shape was synthesized from a layered silicate, kanemite by two steps using solid-state transformation. The mechanical strength (compression strength) of the membrane was greater than 10 kg/cm2. Both sides of the membrane were much different in the morphology and SiO2/Al2O3 ratio. One side (silicalite side) consisted of the intergrowth of prism-like crystals (ca. 1–2 μm), while the other side (mordenite side) was composed of scale-like crystals (ca. > 1 μm). The SiO2/Al2O3 ratios for the respective sides were less than 600 and 15. The XRD patterns were consistent with those of the silicalite and mordenite structures.
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Authors
Yoshimichi Kiyozumi, Takako Nagase, Yasuhisa Hasegawa, Fujio Mizukami,