Article ID Journal Published Year Pages File Type
1652452 Materials Letters 2007 5 Pages PDF
Abstract
Ethylene polymerization was carried out with multiwalled carbon nanotubes (MWCNTs)-supported Cp2ZrCl2 catalyst. Because of the catalyst pretreated on the surface of the MWNTs, the ethylene was expected to polymerize there. The influences of polymerization temperature and Al/Zr molar ratios on the morphologies of the resultant polyethylene were systematically investigated with SEM. The nano-polyethylene fibres were obtained owing to the fibres of original MWNTs were covered by polyethylene. The diameters of the nano-fibres were 80-130 nm. With the increase of reaction temperature, the “over load” of polyethylene on the surface of CNTs made the polyethylene fibres disappear.
Related Topics
Physical Sciences and Engineering Materials Science Nanotechnology
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