Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1657700 | Surface and Coatings Technology | 2013 | 5 Pages |
Nickel oxide (NiO) nanoparticle is a promising material as a p-type semiconductor to replace PEDOT:PSS which is frequently used as a hole transport layer in organic solar cells. In this study, we synthesized Ni/NiO core-shell nanoparticles via direct thermolysis of Ni(acac)2 in the presence of trioctylphosphine oxide ligand and subsequent air oxidation to increase NiO shell thickness. Transmission electron microscopy analysis revealed the core-shell structure of Ni/NiO with average size of ~ 10 nm as well as an increased shell thickness by air-oxidation. The oxidized nanoparticles were well dispersed in organic solvent such as toluene, which can directly form a hole transport layer of organic solar cell by wet coating method. By spin coating various Ni/NiO nanoparticles on the ITO surface, organic solar cells with P3HT:PCBM bulk heterojunction as an active layer were fabricated. Solar cells utilizing air-oxidized Ni/NiO core-shell nanoparticle interlayer exhibited a better performance compared to those utilizing the as-synthesized Ni/NiO layer, or with no interlayer in between ITO and active layer.
► We employ Ni/NiO as OSC interlayer to replace corrosive PEDOT:PSS. ► We employ wet-coating method instead of dry-method to reduce processing cost. ► We show the oxidized Ni/NiO can serve as HTL while the non-oxidized layer doesn't. ► The coating rate was optimized to be 1000 rpm to achieve the best efficiency.