Article ID Journal Published Year Pages File Type
1658320 Surface and Coatings Technology 2012 6 Pages PDF
Abstract

This paper reports the synthesis of hydrophobic and antireflective coatings by sol–gel process at room temperature (25 °C), using tetraethylorthosilicate (TEOS) as a precursor and methyltriethoxysilane (MTES), phenyltriethoxysilane (PTES), vinyltriethoxysilane (VTES), and octyltriethoxysilane (OTES) as surface modifying agents. The silica sol was prepared by keeping the molar ratio of TEOS:RTES at 1:1, in acidic conditions with ethanol and 0.1 M HCl. All hybrid systems were enriched with titanium(IV) isopropoxide as the cross-linking agent. It was observed that the obtained silica films become hydrophobic with the introduction of the hydrophobic organic group. The higher value of static water contact angle (107 ± 3°) was obtained for the silica film prepared with TEOS + OTES. Under optimal synthesis condition, we obtained antireflection coatings, exhibiting a low reflection in the visible range.

► The hydrophobic capacity depends on the organic group of precursors. ► A small decrease of reflection in the visible range for all samples was observed. ► The surfaces of the silica films present small hills and valleys.

Related Topics
Physical Sciences and Engineering Materials Science Nanotechnology
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