Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1665386 | Thin Solid Films | 2014 | 8 Pages |
•Controlled reactive high-power impulse magnetron sputtering was used.•Very high deposition rates of Ta–O–N films were achieved.•Ta–O–N films with tunable composition and properties were produced.•Ta–O–N films with a visible-range optical band gap of 2.5 eV were prepared.
High-power impulse magnetron sputtering of a planar Ta target in various Ar + O2 + N2 gas mixtures was investigated at an average target power density close to 50 W cm− 2 during a deposition. A strongly unbalanced magnetron was driven by a pulsed dc power supply operating at the repetition frequency of 500 Hz and the average target power density of up to 2.4 kW cm− 2 in a pulse with a fixed 50 μs duration. Si(100) and glass substrates were at a floating potential, and the substrate temperatures were less than 285 °C. A pulsed reactive gas (O2 and N2) flow control made it possible to produce high-quality Ta–O–N films of various elemental compositions with high deposition rates of 97–190 nm/min. The film compositions (in at.%) were varied gradually from Ta28O71 with less than 1 at.% of H to Ta38O4N55 with 3 at.% of H. The Ta27O40N31 films with 2 at.% of H, which were produced at the 50% N2 fraction in the reactive gas flow with the highest deposition rate of 190 nm/min achieved, were nanocrystalline with an optical band gap of 2.5 eV and hardness of 8 GPa. These films with a shift of the absorption edge to 500 nm are potential candidates for application as visible-light driven photocatalysts.