| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1666035 | Thin Solid Films | 2013 | 5 Pages |
Abstract
This study investigates the internal oxidation of Nb-Ru multilayer coatings with a cyclically gradient chemical concentration distribution along the growth direction after annealing in a 1% O2-Ar atmosphere at 600 °C for 1 h. X-ray photoelectron spectroscopy and transmission electron microscopy were used to analyze the oxidation behavior of Nb-Ru coatings. The results show that Nb oxidized preferentially in a Nb-Ru coating and partial Nb atoms oxidized to Nb5 +, Nb4 +, and Nb2 +, but Ru remained in a metallic state. After annealing, the microstructure evolved to a laminated structure consisting of alternative crystalline Nb2O5 and Ru layers.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Nanotechnology
Authors
Yung-I Chen, Sin-Min Chen, Li-Chun Chang, Hsiu-Nuan Chu,