Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1669962 | Thin Solid Films | 2010 | 6 Pages |
Abstract
Controlled assembly is the key to harness the nanoscale properties of nanoparticles in most technological applications and it has been an important challenge as it leads to the manipulation of interparticle properties. The present work depicts the control of the assembly of nanoparticles in the monolayers by evaporation kinetics and particle interactions at the air-liquid interface. In the presence of attractive particle-particle and particle-monolayers interactions, nanoparticles self assemble into a superlattice structure upon drying from a colloidal suspension on to the preformed lipid monolayers. This self-assembly mechanism produces monolayers with long-range ordering. However, rapid dewetting and high rate of evaporation can significantly undermine the extent of ordering. Using gold nanoparticles as vehicles for experimentation and by changing the monolayers and solvent, we here demonstrate that the extent of ordering of nanoparticles can be controlled.
Related Topics
Physical Sciences and Engineering
Materials Science
Nanotechnology
Authors
Shweta Gupta, Nahar Singh, Murali Sastry, Rita Kakkar, Renu Pasricha,