Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1672543 | Thin Solid Films | 2009 | 5 Pages |
Abstract
Polyaniline (PANI) emeraldine-base films have been exposed to iodine solutions. The interaction between the films and the iodine solution was studied using the quartz-crystal microbalance (QCM) technique and the UV–visible absorption spectroscopy. The iodine-treated film of emeraldine base was subjected to dedoping process using 0.1 M ammonia solution. The resulting film was exposed again to the previously used iodine solution. Iodine was found to play multiple roles: the ring-iodination of PANI film, the oxidation of PANI to pernigraniline base, and iodine doping to PANI salt. A sensor based on PANI-coated electrode of QCM was developed to monitor the presence of iodine in solution.
Related Topics
Physical Sciences and Engineering
Materials Science
Nanotechnology
Authors
M.M. Ayad, W.A. Amer, J. Stejskal,