Heteroepitaxial growth of layered semiconductors, LaZnOPn (Pn = P and As)

LaZnOPn (Pn = P and As) thin films were successfully grown on MgO (001) substrates with an epitaxial relationship of (001) LaZnOPn || (001) MgO and [110] LaZnOPn || [110] MgO. The electrical conductivity of undoped LaZnOP epitaxial film was so low, 3.1 × 10− 6 S/cm at room temperature, that reliable Seebeck and Hall measurement results were not obtained. On the other hand, the electrical conductivities of the Cu-doped LaZnOP and undoped LaZnOAs epitaxial films were 2.7 × 10− 2 and 2.0 × 10− 1 S/cm at room temperature, respectively. The Seebeck coefficients of both the epitaxial films were positive, indicating p-type semiconductors. The optical bandgaps of LaZnOP and LaZnOAs were estimated to be ∼ 1.7 eV and ∼ 1.5 eV, respectively.