Modeling and numerical study of electrical characteristics of polymer light-emitting diodes containing an insulating buffer layer

In order to improve the electrical characteristic of polymer light-emitting diodes, a simple model for the device characteristic with an insulating buffer layer at cathode is proposed. This model is based on Fowleer–Nordhein tunneling mechanism and Poission's equation. An additional tunneling factor which characterises the tunneling effect of buffer layer is introduced. The simulated current–voltage characteristic indicates how an insulating buffer layer with suitable thickness decreases the barrier height at the cathode and therefore increases the electron injection. The model is validated by experimental results of devices with BaO as the buffer material and poly[2-methoxy-5-(2′-ethyl-hexyloxy)-1,4-phenylenevinylene] as the emission material. An optimum thickness of the buffer layer is also obtained from the model, which provides a guide to device design.