Multiple linear equation of pore structure and coal–oxygen diffusion on low temperature oxidation process of lignite

This work aimed at studying the feasibility of calculating the coal–oxygen diffusion properties during the low temperature oxidation process of lignite so as to predict its spontaneous combustion process. Coal samples were oxidized in air ambient under different temperatures. Scanning Electron Microscope was used to indicate the surface morphology changes of oxidization. Then, based on fractal theory and flow characteristics, the fractal dimension of gas diffusion in the pore ways was calculated under different temperature. Considering pore size distribution, connectivity distribution and Fick diffusion mechanisms, the relationship between the gas diffusivity change with pore area fractal dimension and porosity was investigated, and multiple linear equation of the coal–oxygen diffusion coefficients and pore parameters was obtained. Comparison between the experimental data and model prediction verifies the validity of the model. The research provides a theoretical basis for the prediction model of coal–oxygen diffusion law.

Graphical abstractThe relationship among oxygen diffusion coefficient, average pore diameter and fractal dimension is shown in figure. The coal–oxygen diffusion coefficient increases with the average pore diameter but decreases with the fractal dimension, and both of them have good linear relationship.Figure optionsDownload full-size imageDownload as PowerPoint slide