Article ID Journal Published Year Pages File Type
1683684 Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 2010 6 Pages PDF
Abstract

PEO(1 − x)NH4ClO4(x) samples with x = 0.18 are irradiated with gamma doses varying up to 50 kGy. DSC and XRD studies indicate, in general, a decrease in crystallinity with dose. Measurement of viscosity of aqueous solutions of the irradiated samples at the same concentration, shows that there is overall chain scission on irradiation, though there is evidence of some cross-linking also at higher doses. This is corroborated by FTIR measurements. The ion-conductivity shows a strong increase for irradiation dose 35 kGy. This suggests that there is a possibility of improving polymer electrolyte properties on gamma irradiation.

Related Topics
Physical Sciences and Engineering Materials Science Surfaces, Coatings and Films
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