Article ID Journal Published Year Pages File Type
168372 Chinese Journal of Chemical Engineering 2006 4 Pages PDF
Abstract

Alkyl-substituted ferrocenium salts have limited solubility in epoxy oligomers and produce poisonous arene by photolysis. Herein, the synthesis and photoactivity of several alkoxy-substituted ferrocenium salts as long-wavelength UV light photoinitiators have been reported. [Cyclopendadien-Fe-anisole]PF6, [Cyclopen-dadien-Fe-anisole]BF4, [Cyclopendadien-Fe-diphenylether]PF6, [Cyclopendadien-Fe-diphenylether]BF4, and [Cyclopendadien-Fe-diethoxybenzene] PF6 for polymerization of epoxy resin were prepared through the ligand exchange reaction between one ring of ferrocene and aromatic ether. They all display good solubility and photoini-tiating activities in epoxy resins.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)