Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1686207 | Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms | 2011 | 4 Pages |
Abstract
We report first results on the deposition of l-cysteine (Cys), a fundamental amino-acid, on a magnetic substrate. Molecules have been deposited under ultra-high vacuum conditions on Fe(1Â 0Â 0) films. Electronic and magnetic properties of adsorbed molecules have been investigated by spin polarized metastable deexcitation spectroscopy (SPMDS). The spectra show a growth dynamics apparently similar to the one already reported on coinage metal surfaces with the formation of a strongly-bound thiolate species (SFe bond) and weakly-bound second-layer molecules. SPMDS revealed the spin-polarized character of an Auger (Penning) deexcitation peak related to a Cys molecular orbital. Interestingly, these spin-polarization effects, ascribed to the interaction with the magnetized substrate, vanish before the first layer completion, suggesting a possible correlation with the SAM assembly properties.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Surfaces, Coatings and Films
Authors
L. Lavagnino, R. Moroni, F. Bisio, S. Terreni, L. Mattera, M. Canepa,