Article ID Journal Published Year Pages File Type
1696606 Applied Clay Science 2007 7 Pages PDF
Abstract

Quaternary phosphonium cations (hexadecyl tributyphosphonium; tetradecyl tributylphosphonium; tetraphenylphosphonium; methyl triphenylphosphonium; ethyl triphenylphosphonium and propyl triphenylphosphonium) were intercalated into montmorillonite (MMT) rich bentonite of Indian origin, by ion exchange reaction. The phosphonium MMT were characterized by Fourier transform infrared spectroscopy (FTIR), powder X-ray diffraction analysis (PXRD), particle size distribution (PSD) and thermogravimetric analysis (TGA). The phosphonium cations significantly influenced the particle size distribution. With longer alkyl chain finer particles were formed. The tetrabutylphosphonium and tetraphenylphosphonium MMT showed enhanced thermal stability (300–400 °C) and may be potentially useful materials for melt processing of polymer/layered silicates nanocomposites.

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Physical Sciences and Engineering Earth and Planetary Sciences Geochemistry and Petrology
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