Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
170290 | Comptes Rendus Chimie | 2015 | 6 Pages |
Abstract
We herein report on a novel, simple and straightforward method for the preparation of nickel bisdiphosphine hydrogen-evolving catalysts, so-called DuBois catalysts, from commercially available nickel hexaaqua salts. This method yields coordination complexes with the same physical characteristics as previously described for compounds prepared from the [Ni(CH3CN)6]2+ precursor. However, if hexaaquanickel(II) chloride is used as a precursor, a different nickel bisdiphosphine complex is formed, which incorporates chloride as an axial ligand. This complex displays a significantly different electrochemical behavior and a diminished activity for proton reduction as compared to classic DuBois catalysts.
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Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Reuben T. Jane, Phong D. Tran, Eugen S. Andreiadis, Jacques Pécaut, Vincent Artero,