Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
170524 | Comptes Rendus Chimie | 2014 | 5 Pages |
Abstract
Structure sensitivity in heterogeneous catalytic oxidative dehydrogenation of lignan hydroxymatairesinol (HMR) extracted from Norway spruce knots was investigated over a series of alumina-supported gold catalysts. A mathematical model was developed based on the concept of noncompetitive adsorption of reactants. The model, being consistent with kinetic regularities, such as reaction orders in reactants, explains well the dependence of catalytic activity on the gold cluster size.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Olga A. Simakova, Elena V. Murzina, Dmitry Yu. Murzin,